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Introductory PHP Tutorials:
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(in no particular order)

Introduction to PHP :
   http://www.gimpster.com/wiki/PhpTutorial
   - Basic, for the newbie.

Introduction to PHP :
   http://www.devshed.com/Server_Side/PHP/PHP101_1/
   - First of a Five part series on Devshed on the basics of PHP. 
     You really should check these out.

PHP Intro Review:
   http://www.builder.com/Programming/PHPIntro/
   - The folks at C|Net made a nice Intro to PHP

Vattekkat takes a stab at answering "What is PHP?"
   http://vsbabu.org/tutorials/php/
   - An overview on what PHP is. with samples.

PHP and MYSQL Basics (a bit MySQL oriented so ... )
   http://www.hotwired.com/webmonkey/databases/tutorials/tutorial4.html
   - Used to be the 'only' basic PHP article out there, still
     really good.  Deals a lot with PHP/MySQL together.

Using Strings with PHP
   http://www.zend.com/zend/tut/using-strings.php
   - This is VERY nice.  Print this out and read/reread.

PHPBuilder.com shares real-world uses with PHP
   http://www.phpbuilder.com/
   - If you're serious about PHP, bookmark this site.

PHP Links
   http://www.php.net/links
   - A list of PHP related links